catena-Poly[[dibromidozinc(II)]-μ-3-(1H-benzimidazol-2-yl)[2,6-2H2]pyridine N-oxide]
نویسندگان
چکیده
In the crystal structure of the title compound, [ZnBr(2)(C(12)H(7)D(2)N(3)O)](n), the Zn atoms are coordinated by two Br atoms and by one N atom and one O atom of two symmetry-related 3-(1H-benzimidazol-2-yl)[2,6-(2)H(2)]pyridine N-oxide ligands in a slightly distorted tetra-hedral geometry. The ZnBr(2) units are connected by the organic ligands into chains.
منابع مشابه
catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN 3)-1,2,3-triazol-1-ido-κ2 N 1:N 3]
In the title complex, [Zn(C(10)H(8)N(5))Cl](n), the Zn(II) ion is four-coordinated by one Cl atom and three N atoms from two in situ-generated deprotonated 5-(1-methyl-1H-benzimidazol-2-yl-κN(3))-1,2,3-triazol-1-ide ligands in a slightly distorted tetra-hedral geometry. The Zn(II) ions are bridged by the ligands, forming a helical chain along [001]. C-H⋯N and C-H⋯Cl hydrogen bonds and π-π inter...
متن کاملcatena-Poly[[[dichloridozinc(II)]-μ-1,4-bis(1H-benzimidazol-2-yl-κN 3)butane] 1,4-bis(1H-benzimidazol-2-yl)butane solvate]
In the crystal structure of the title coordination polymer/co-crystal, {[ZnCl(2)(C(18)H(18)N(4))]·C(18)H(18)N(4)}(n), the tetrahedrally coordinated Zn(II) ions are linked by the N-heterocycle into a linear chain. Another N-heterocycle present is not coordinated to the metal atom but inter-acts with the chain through N-H⋯N and N-H⋯Cl hydrogen bonds. The butyl chain of the uncoordinated ligand is...
متن کاملBis[2,6-bis(1H-benzimidazol-2-yl)pyridine]nickel(II) dipicrate dimethylformamide disolvate
In the title compound, [Ni(C(19)H(13)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Ni(II) ion is coordinated by two tridentate 2,6-bis-(1H-benzimidazol-2-yl)pyridine ligands in a distorted octa-hedral geometry. In the crystal structure, the picrate anions and solvent dimethyl-formamide (DMF) mol-ecules are connected to the cation via inter-molecular N-H⋯O hydrogen bonds. Further stabilization...
متن کاملcatena-Poly[[dibromidozinc(II)]-μ-4-(3-pyridyl)-4H-1,2,4-triazole]
The title complex, [ZnBr(2)(C(7)H(6)N(4))](n), was formed under hydro-thermal conditions using the ligand 4-(3-pyrid-yl)-4H-1,2,4-triazole (L). The unique Zn(II) ion is coordinated by one triazole N atom, one pyridine N atom and two Br atoms in a slightly distorted tetra-hedral coordination environment. Symmetry-related Zn(II) ions are connected by bridging L ligands into chains parallel to [00...
متن کاملBis[2,6-bis(1-methyl-1H-benzimidazol-2-yl-κN 3)pyridine-κN]zinc dipicrate methanol disolvate
In the title compound, [Zn(C(21)H(17)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2CH(3)OH, the Zn(II) atom is coordinated by six N atoms from two tridentate 2,6-bis-(1-methyl-1H-benzimidazol-2-yl)pyridine ligands in a distorted octa-hedral environment. In the crystal, the picrate anions and methanol solvent mol-ecules are connected by O-H⋯O hydrogen bonds. Weak inter-molecular C-H⋯O hydrogen bonds are also ...
متن کامل